Go ahead and use the starter motor, AFTER you remove the spark plugs.
When you get the cylinders blown-out, you'll find TDC-Compression by looking for pressure in #1 as the crank is turned. (You can watch the valves to assure they're both closed, if the valve cover is removed.) Remember that at TDC-Exhaust, both valves are ALMOST closed, (open on overlap) and may in fact close if the lifters leak down quickly. So you'd want to watch the intake valve close, and then turn the crank to TDC.
From there, the distributor-setting procedure for Vortec engines is in the service manual. STRONGLY recommend you download the service manual set for your vehicle from the links in the Sticky thread section of the Engine forum, and read it.