That would be the heater hose "quick connect" fitting and they're notorious for breaking. Subject is covered a lot here if you do a search. You'll want to take care removing the remains of the fitting from the intake manifold so that you don't hurt the threads.
Richard
I'm taking your advice ...I took intake manifold to trusted local engine machine shop to clean & repaint and remove busted piece of that cooling tube & hose...truck is getting new reman 454 long block and for simplicity and ease of repairs and keeping this old truck on the road I decided at the very beginning to keep drivetrain 100% factory original stock configuration including EGR, catalytic converter, TBI, air cleaner assembly, and intake manifold...so even though that cast iron intake manifold is 4million lbs and crusty with rust and grease, I'm keeping it and getting it cleaned, repainted, and have engine shop use their experience to remove that busted metal cooling piece broken off in the manifold...I'll have same machine shop clean up the exhaust manifolds next so I can re-use them as well
Overall...I greatly underestimated how much repair & restoration this 1991 Chevy k3500 would require to get back to reliable daily driver condition...at least here in Colorado we don't worry about rust as badly as many other parts of north America but mechanically much of this truck was just worn out and busted...paid $2500 for it back in March 2023 and drove it 30 miles home breaking down a few times but finally got home...I've easily "invested" about $10k+ in parts/work since then and now I'm replacing the 454 motor with a NAPA reman bbc long block and that'll end up $5k after it's all said & done. No plans to ever sell this truck but thus far I'm already learning the Gen5 vortec cast iron big blocks have timing chain stretch problems as they get over 100k miles which lead to engine failure...would double roller timing chain help extend lifespan of motor?